Stability of pentlandite in the Fe-Ni-Co-S system     

H. Kaneda  S. Takenouchi  T. Shoji 《Mineralium Deposita》1986,21(3):169-180

Pentlandite has a wide compositional range in the Fe-Ni-Co-S system and the Fe-Ni-S system. The metal : sulfur atomic ratio is approximately 9 : 8. The Co content of pentlandite from the Kamaishi ore deposit and one from the Outokumpu ore deposit (Knop et al. 1965) varies from a Co-free to nearly a Co₉S₈ composition. Pentlandite forms a complete solid solution between (Fe, Ni)_9±x S₈ and Co_9±x S₈ in the 600°–300°C temperature range. On the other hand, it is presumed that the pentlandite solid solution decomposes into two fields toward the (Fe, Ni)₉S₈ and Co₉S₈ members at 200°C. The field of solid solution at 500°C is the most extensive and includes all of the other solid-solution fields. The metal : sulfur ratio of the solid solution varies systematically, i.e., the Fe-rich field sinks toward the Fe-Ni-Co plane away from the M₉S₈ section, and contrarily the Ni-rich field shifts toward the sulfur apex. The d ₀₄₄ value decreases with increasing S, Ni, or Co contents in pentlandite. The Kamaishi pentlandites, Iwate Prefecture, Japan, lie within or close to the solid-solution field at 300°C, showing a very good correlation with the Co : Ni ratio of the homogeneous natural pyrrhotite phase.  相似文献   

Chromian spinel lamellae in olivine from the Iwanai-dake peridotite mass,Hokkaido, Japan     

Shoji Arai 《Earth and Planetary Science Letters》1978,39(2):267-273

Lamellar inclusions of chromian spinel (Cr/Cr + Al> 0.7), clinopyroxene and chromian spinel-clinopyroxene symplectite occur in olivines from alpine-type peridotites which have equilibrated at relatively low temperature (<700°C). They occur most commonly in dunite with very magnesian olivine (Fo₉₃ to Fo₉₅) and discrete grains of Cr-rich spinel. Olivine which initially equilibrated with magnesian and Cr-rich liquid had contained small amounts of calcium and trivalent chromium in the octahedral site, and lamellar chromian spinel and diopsidic clinopyroxene exsolved during the annealing process. The ordinary depletion of chromium or absence of chromian spinel lamellae in olivines in igneous rocks may be partly due to the effective exclusion of chromium from olivine upon cooling.  相似文献   

One-armed oscillations of a non-selfgravitating polytropic disk     

Atsuo T. Okazaki  Shoji Kato 《Astrophysics and Space Science》1986,119(1):109-110

One-armedglobal oscillations in a non-selfgravitating polytropic disk rotating around a star are investigated. The unperturbed disk is axisymmetric, geometrically thin, and extends infinitely in the radial direction keeping its thickness constant. Perturbations considered are inviscid and adiabatic. It is found that there are one-armed retrograde wave modes which are trapped in an inner region of the disk. The eignefrequency of the lowest order mode is given by _K(r _s)(z ₀/r _s)₂, wherer _s is the radius of the central star,z ₀ is the half-thickness of the disk, and _K(r _s) is the Keplerian angular frequency at the surface of the star.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.  相似文献   

Distribution of gold and silver and its relation with hypogene ore minerals in the Esperanza porphyry deposit,Antofagasta Region,Chile     

Shoji Kojima  María Constanza San Martín  Toshiro Nagase  Daisuke Nakashima  Claudio Bisso  Andrew Menzies 《Resource Geology》2021,71(1):80-90

Modes of occurrence of Au‐ and Ag‐bearing phases and their relation with associated hypogene ore minerals were examined with the objective to elucidate Au‐Ag distribution at the Esperanza porphyry deposit in the Eocene Centinela copper belt, using ore‐microscope modal analysis, semi‐quantitative analyses by automated mineralogy, electron probe microanalysis, and secondary ion mass spectrometer. The Esperanza hypogene mineralization is characterized by early‐stage chalcopyrite‐rich veinlets in the potassic alteration zone and later polymetallic stage with tennantite and galena in the chlorite‐sericitic alteration zone. Only the early‐stage chalcopyrite contains fine‐grained electrum (Au₆₈Ag₃₂ ‐ Au₈₁Ag₁₉) and hessite (Ag₂Te), and thus yields positive correlations in Cu vs. Au and Cu vs. Ag grades that are clearly recognized in the hypogene sulfide zone. The early‐stage chalcopyrite grains frequently exhibit polysynthetic twinning suggestive of inversion from intermediate solid solution. These features suggest that the fine‐grained electrum and hessite are products exsolved in the cooling process with the intermediate solid solution to chalcopyrite inversion. In contrast, tennantite and galena of the later‐stage mineralization contain no detectable Ag, and it is thus proposed that the early‐stage inverted chalcopyrite is the principal storage of economically important precious metals.  相似文献   

Molybdenite Mineralization and Re‐Os Geochronology of the Escondida and Escondida Norte Porphyry Deposits,Northern Chile     

Bárbara Romero  Shoji Kojima  Chilong Wong  Walter Véliz  Joaquin Ruiz 《Resource Geology》2011,61(1):91-100

Molybdenum is an economically important subproduct of North Chilean porphyry‐type deposits, and thus spatial and temporal distribution of molybdenite as the primary Mo‐bearing mineral in the Escondida and Escondida Norte deposits were characterized using several mineralogical and chemical techniques and the Re‐Os dating method. Molybdenum is distributed extensively in the two deposits, and high molybdenum concentrations (>500 ppm) are recognized particularly in the chlorite‐sericite transitional zone between the potassic and sericitic zones. Two modes of occurrence of molybdenite are observed in the Escondida deposit: aggregates with Cu‐Fe‐sulfide minerals in fine veinlets (sulfide‐veinlet type), and monomineralic microveinlets associated with NE‐trending faults. The former and the latter yielded ages of 36.1 ± 0.2 Ma and 35.2 ± 0.2 Ma, respectively. Re‐Os dating of Escondida Norte molybdenites also show two distinct episodes, at 37.7 ± 0.3 Ma and a younger episode at 36.6 ± 0.2 Ma. These data indicate that the Escondida Norte is older than the main Escondida deposit. The Re‐Os age data combined with those of the porphyry emplacement suggest that the molybdenite mineralization in the Escondida district occurred as several short episodic pulses during the late‐magmatic to hydrothermal transition, and that the Cu‐Mo deposits were formed in a variable overall period spanning 1 to 5 m.y.  相似文献   

Reconnaissance report on landslide disasters in northeast Japan following the M 9 T��hoku earthquake     

Toyohiko Miyagi  Daisuke Higaki  Hiroshi Yagi  Shoji Doshida  Noriyuki Chiba  Jun Umemura  Go Satoh 《Landslides》2011,8(3):339-342

An earthquake of M_w 9.0 struck the Pacific coast in northeast Japan on March 11, 2011 and was followed by a hugely damaging tsunami along 500 km of the Japanese coastline. An inland aftershock of M. 7.0 occurred on April 11; during which, surface fault ruptures appeared on land. A large variety of landslide disasters resulted from these earthquakes in various parts of northeastern Honshu, Japan. The full extent of the landslides is still being determined. This brief report introduces some of the landslide phenomena so far investigated by the Japanese Landslide Society. These are (1) failure of a water reservoir embankment dam in Sukagawa, Fukushima prefecture, (2) landslides and surface seismic fault rupture from the April 11 aftershock in Iwaki, Fukushima, (3) a concentration of surface failures at Matsushima Bay in Miyagi prefecture, and (4) small landslides on modified slopes in residential areas around Sendai city.  相似文献   

Compositional variations in spinel-hosted pargasite inclusions in the olivine-rich rock from the oceanic crust–mantle boundary zone     

Akihiro Tamura  Tomoaki Morishita  Satoko Ishimaru  Kaori Hara  Alessio Sanfilippo  Shoji Arai 《Contributions to Mineralogy and Petrology》2016,171(5):39

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Peridotite xenoliths from the Shiribeshi Seamount,Japan Sea: insights into mantle processes in a back-arc basin     

Yuji Ichiyama  Tomoaki Morishita  Akihiro Tamura  Shoji Arai 《Contributions to Mineralogy and Petrology》2016,171(10):86

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Possible variation in methane flux caused by gas hydrate formation on the northeastern continental slope off Sakhalin Island, Russia     

Hirotsugu Minami  Kazuya Tatsumi  Akihiro Hachikubo  Satoshi Yamashita  Hirotoshi Sakagami  Nobuo Takahashi  Hitoshi Shoji  Young Keun Jin  Anatoly Obzhirov  Nataliya Nikolaeva  Alexander Derkachev 《Geo-Marine Letters》2012,32(5-6):525-534

The Sakhalin Slope Gas Hydrate Project (SSGH) is an international collaborative effort by scientists from Japan, Korea, and Russia to investigate natural gas hydrates (GHs) that have accumulated on the continental slope off Sakhalin Island, Okhotsk Sea. From 2009 to 2011, field operations of the SSGH-09, -10, and -11 projects were conducted. GH-bearing and -free sediment cores were retrieved using steel hydro- and gravity corers. The concentrations of sulfate ions in sediment pore waters were measured to investigate sulfate concentration–depth profiles. Seventeen cores showed linear depth profiles of sulfate concentrations. In contrast, eight cores and two cores showed concave-up and -down profiles plausibly explained by sudden increase and decrease in methane flux from below, respectively, presumably caused by the formation of gas hydrate adjacent to the core sampling sites.  相似文献   

Chromitite and peridotite from Rayat, northeastern Iraq, as fragments of a Tethyan ophiolite     

Sabah A.  Ismail  Shoji  Arai  Ahmed H.  Ahmed  Yohei  Shimizu 《Island Arc》2009,18(1):175-183

Ophiolitic rocks (chromitites and serpentinized peridotites) were petrologically examined in detail for the first time from Rayat, in the Iraqi part of the Zagros thrust zone, an ophiolitic belt. Almost all the primary silicates have been altered out, but chromian spinel has survived from alteration and gives information about the primary petrological characteristics. The protolith of the serpentinite was clinopyroxene-free harzburgite with chromian spinel of intermediate Cr# (= Cr/[Cr + Al] atomic ratio) of 0.5 to 0.6. The harzburgite with that signature is the most common in the mantle section of the Tethyan ophiolites such as the Oman ophiolite, and is the most suitable host for chromitite genesis. Except for one sample, which has Cr# = 0.6 for spinel, the Cr# of spinel is high, around 0.7, in chromitite. The variation in Cr# of spinel in chromitite observed here has been also reported in the Oman ophiolite. The peridotite with chromitite pods exposed at Rayat was derived from an ophiolite similar in petrological character to the Oman ophiolite, one of the typical Tethyan ophiolites (fragments of Tethyan oceanic lithosphere). This result is consistent with the previous interpretation based on geological analysis.  相似文献